Thermodynamics in Geochemistry: The Equilibrium ModelOxford University Press, 17. lip 1993. - Broj stranica: 608 This textbook and reference outlines the fundamental principles of thermodynamics, emphasizing applications in geochemistry. The work is distinguished by its comprehensive, balanced coverage and its rigorous presentation. The authors bring years of teaching experience to the work, and have attempted to particularly address those areas where other texts on the subject have provided inadequate coverage. A thorough review of the necessary mathematics is presented early on, both as a refresher for those with a background in university calculus, and for the benefit of those coming to the subject for the first time. The text is written for students in advanced undergraduate or graduate-level geochemistry as well as for all researchers in this field. |
Sadržaj
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| 7 | |
3 THERMODYNAMIC TERMS | 37 |
4 THE FIRST LAW OF THERMODYNAMICS | 60 |
5 THE SECOND LAW OF THERMODYNAMICS | 83 |
6 STATISTICAL INTERPRETATION OF ENTROPY | 116 |
7 THERMODYNAMIC PROPERTIES OF SIMPLE SYSTEMS | 146 |
8 APPLICATIONS TO SIMPLE SYSTEMS | 184 |
13 THE EQUILIBRIUM CONSTANT | 295 |
14 HETEROGENEOUS AND OPEN SYSTEMS | 323 |
15 SOLID SOLUTIONS | 364 |
16 GASEOUS SOLUTIONS | 397 |
17 AQUEOUS ELECTROLYTE SOLUTIONS | 418 |
18 REDOX SYSTEMS | 469 |
19 SPECIATION CALCULATIONS | 505 |
APPENDIXES | 541 |
9 PARTIAL AND APPARENT MOLAR PROPERTIES | 210 |
10 IDEAL SOLUTIONS | 228 |
11 FUGACITY AND ACTIVITY | 244 |
12 STANDARD STATES | 269 |
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Ostala izdanja - Prikaži sve
Thermodynamics in Geochemistry: The Equilibrium Model Gregor Munro Anderson,David A. Crerar Ograničeni pregled - 1993 |
Uobičajeni izrazi i fraze
activity coefficients adiabatic aqueous assemblage buffered calcite calculated cell Chapter chemical potential coexist completely components composition concentration configuration consider constituents constraint curve defined derived diagram differential dilute discussed dissol'n electrolyte elements energy levels enthalpy entropy equilibrium constant example experimental expression fixed fo₂ formation fugacity function gaseous gases Gibbs free energy half-cell heat capacity Helgeson Henry's Law ideal gas ideal solution integration interactions ionic ions liquid mass measured metastable minerals mixture molal mole fraction molecules NaCl NDIM non-ideal oxidation parameters partial molar volume Phase Rule Pitzer Pitzer equations pressure problem pure quantity quartz Raoult's Law reaction reference relationship salt shown in Figure simple SiO2 sol'n solid solutions solvus species stable equilibrium standard temperature thermodynamic potentials thermodynamic properties values vapor variables virial equation X₁ zero ΔΗ μα ат ӘР
Popularni odlomci
Stranica 574 - Garrels, RM, and Thompson, ME, 1962, A chemical model for sea water at 25°C and one atmosphere total pressure : Am.
Stranica 576 - Huebner JS (1971) Buffering techniques for hydrostatic systems at elevated pressures. In Research Techniques for High Pressure and High Temperature (Gene C.
Stranica 574 - Silicic acid ionization and calculation of silica solubility at elevated temperature and pH: application to geothermal fluid treatment and reinjection.
Stranica 574 - Chapter 13 in HJ Greenwood, ed., Short Course in Application of Thermodynamics to Petrology and Ore Deposits, Toronto, Mineral.